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元素同元素之間既結合有無法則??

No, those are only the descriptions of existing chemical interactions between elements, not the rules that guide the formation of susbtances from elements.

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In fact one can figure out why O2 is formed instead of O3 in your example through theoretical modeling. Of course, the reasons will be on case-by-case basis, and may not be easily generalized for all possible cases.

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